Just in case @
Hamish comes back (and seeing as I've got time to kill).
The problem is that you only asked half a question. I'm assuming due to the mAh ratings you gave that you mean some sort of eGo battery but there are different makes/types of eGo and they can behave differently.
A Joyetech or Janty eGo battery has a regulated output. Within the connector is a small circuit board that maintains the output at 3.4V (ish) until the battery has discharged.
The new Joyetech upgrade eGo batteries can be switched to remove the voltage regulation. They can either output a regulated 3.4V (ish) or you can switch it to unregulated and it will start hot off a charger at 4.2V and the voltage drops through use until the battery is discharged.
There is also the eGo Twist batteries and the Vision Spinner batteries which are variable voltage but are regulated. You can set the output to your desired voltage and the battery will output that voltage until it has discharged.
There are also Riva eGo style batteries which are (I believe) unregulated and so start off hot from the charger at about 4.2V which slowly drop until the battery is discharged.
There are also vGo batteries which I'd have to check as their are now different types.
Then there are batteries which are meant to be put into devices rather than be the device. The most common sizes used for e-ciggery pokery are 18350, 18500 and 18650. The device they are put in will determine whether the output is regulated or not.
Basically, every battery starts at a voltage but drops off through a charge. This can be taken into account using a regulator circuit. The mAh rating does not matter as to what voltage these batteries will output but it does determine how long it will take to go from fully charged to discharged.
If you tell us what battery you are enquiring about we can cut down on the possibilities.
Hope you read this before you buy a battery that doesn't do what you want.
I quite enjoyed writing this post