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Formaldehyde release in e-cigarette vapour, - Dr F's response

Gonloopy

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The New York Times story explained in detail

Dr Farsalinos


A study to be published in Nicotine and Tobacco Research was featured in the New York Times and has generated a lot of interest. The article mentioned that e-cigarette vapor can be the source of carcinogens, depending on the heating process.


The article is true and expected. We know that thermal degradation can lead to the release of toxic chemicals. And we know that formaldehyde, acetaldehyde and acrolein have been found in vapor. There is nothing new to it. However, this study found that levels may approach those present in tobacco cigarettes.


Herein, I present with more detail the results of this study. Researchers used an EGO Twist battery (variable voltage) and a top-coil clearomizer (with unknown resistance, thus unknown wattage delivery). At 3.2 and 4.0 volts, formaldehyde levels were 13-807 times lower compared to tobacco cigarettes!! At 4.8 volts, formaldehyde levels were increased by up to 200 times, and reached to levels similar to tobacco cigarettes.


The main criticism to this study is that in my opinion it is highly unlikely that a top-coil atomizer like the one used in this study would be used at 4.8 volts. At a resistance of 2.2 Ohms that would represent 10.4 watts of energy delivery to the atomizer. I tried 10 watts with an EVIC battery in a Vivi Nova top-coil atomizer, and many vapers were unable to use it due to the dry puff phenomenon.It is very important to examine new-generation (rebuildable or bottom coil) atomizers, who are more likely to be used at higher voltages. I am certain that, due to better liquid resupply to the resistance and wick, the results will be much more favorable.


Another important point is that, although formaldehyde levels can be similar to tobacco, several other toxic chemicals are completely absent from e-cigarette vapor. For example, acrolein was completely absent although they used liquids with glycerol as the main ingredient. In fact, glycerin-based liquids had much lower formaldehyde levels in vapor compared to PG or PG/VG liquids, suggesting that they are much safer to use. As a general remark, finding few chemicals at similar levels does not mean that the risk is equivalent to tobacco cigarettes.


Concerning the remarks about dripping, we should admit that dripping does not allow the user to see how much liquid is present in the atomizer. The same happens with cartomizers. Thus, clearomizer-type atomizers seem to be the future in e-cigarette use, giving consumers the ability to know when they need to resupply the atomizer with liquid
 
Yup dry hits taste awful. But did they really test dry hits or is high wattage Vaping the problem?

Sent from my Nexus 5 using Planet of the Vapes mobile app
 
I read this as dry hits, - which you are more likely to get at higher wattages.
:)
 
I read this as dry hits, - which you are more likely to get at higher wattages.
:)


Interesting quote. Top coil clearo' at high wattage/voltage with seal at top of coil?

Formaldehyde is thermally generated from many materials -- including high consistency silicone rubber.
However, the rate at which silicone rubber generates formaldehyde is substantially lower than many
common materials. Silicone rubber begins to generate formaldehyde at temperatures as low as 149oC, but
does not appreciably generate formaldehyde until ~200oC and above.
 
Interesting quote. Top coil clearo' at high wattage/voltage with seal at top of coil?

Formaldehyde is thermally generated from many materials -- including high consistency silicone rubber.
However, the rate at which silicone rubber generates formaldehyde is substantially lower than many
common materials. Silicone rubber begins to generate formaldehyde at temperatures as low as 149oC, but
does not appreciably generate formaldehyde until ~200oC and above.

Yes I'm not sure that it purely silicone that is the culprit though. As it say above, it's been found before and has been related to overheating. Here is the link to Dr Farsalinos presentation to the ecig summit in 2013 if you want to delve into this any deeper :D
E-Cigarette Summit - Dr. Konstantinos Farsalinos - ECF InfoZone
 
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